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PMeT is a more common ob-iect of investigation than the structurally simpler PT, because the extra methyl group guarantees 0 - 0coupling and thus affords a more defined polymer. Interpretation of the lines as C=C stretching: 1470 cm-l and as thiophene ring deformation: 722 cm is based on comparison with PT (Furukawa et al., 1987) and on force field calculations (Faulques et al., 1989). The ground state of the neutral polymer was found to be aromatic, whereas the doped state is quinoid. This is a simple consequence of the formation of bipolarons, since the structure between two bipolarons is quinoid. PPy behaves very much like PT and PMeT, but has a slightly larger energy gapPITN has attracted considerable attention because of its strongly reduced gap even in the neutral state (Bredas, 1985). Since doping shifts absorption to a lower energy level, this polymer becomes highly transparent in the doped state. Assignment to vibrational modes is based on comparison to PT and benzene and on a force field analysis (Faulques et al., 1989; Wallnoefer et al., 1989a). Two types of Raman lines have been observed: a set of resonance-enhanced lines, which have been attributed to the neutral polymer, and another set of non-resonant-enhanced modes, attributed to the doped polymer. Interestingly, it was concluded from Raman experiments that the ground state of PITN is quinoid, whereas the doped state is aromatic. This experimental result was confirmed by a quantum chemical calculation (Lee and Kertesz, 1988). Thus, with respect to the ring structure, PITN behaves contrary to PT. PPV is attractive because it can be prepared as a stretch-oriented material with considerable anisotropic properties. Stretch orientation is introduced via a precursor of the polymer. The lines at 1330 and 1628 cm have been

initialize array Dim myArray(9) set array values For i = 0 to 9 myArray(i) = Placeholder & i Next display array values For Each i IN myArray WScript.Echo i Next continued

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thus becoming stable again. Subsequent solvent evaporation can, of course, bring this droplet back to the unstable conditions, resulting in another ssion event (Figure A.1). Eventually, charges on both the precursor and the progeny droplets will be reduced to such levels that further solvent evaporation will no longer bring about Rayleigh instability. Complete evaporation of solvent from the droplets will, therefore, force the residual charge onto the solute molecules. The solute molecules are assumed to be large macromolecules that either lack charge in solution or else maintain electroneutrality through association with counterions. This scenario forms the foundation of the so-called charge residue model (CRM) of ion formation, which is attributed to Dole et al. (23). It should probably be mentioned here once again that despite the violent nature of the charged jet breakup and subsequent Coulombic explosions of the electrospray droplets, the bulk of the liquid may remain essentially charge- and eld-free (24). Given the suf ciently high concentration of charge carrier in the liquid, a quasi-equilibrium charge layer will be formed at the liquid gas interface. As a result, even the weakly conducting liquid would conform to a quasi-electrostatic model with the charge con ned to the surface and the bulk of the liquid remaining quasi-neutral and eld-free. This assertion, however, is not universally accepted (e.g., see (12)). Therefore, the solute molecules residing in the bulk of the liquid will remain oblivious to the harsh conditions on the droplet surface and the environment beyond it until the last of the solvent is gone. Indeed, there is solid evidence that proteins do not denature during droplet evolution in the course of ESI (25). This

Governments worldwide have seen the wisdom of implementing PKI, and they represent a very important vertical market segment for those selling PKI products. The security needs of governments are comprehensive, and PKI provides an excellent framework for meeting them. For example, an important U.S. government initiative related to PKI is the General Services Administration (GSA) Access Certificates for Electronic Services (ACES) program. The vision behind the ACES program is to provide a common PKI for granting public and government vendors electronic access to privacy-related U.S. government information and services. ACES has the goal of providing individuals and business entities that are communicating with the government identification, authentication, and nonrepudiation services when accessing, retrieving, and submitting information. Commercial PKI service companies that meet published ACES requirements and have been approved by the GSA will be permitted to issue certificates under the ACES program. More information on the ACES program can be found on GSA s Web site at www.gsa.gov/aces.

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When you open a datasheet in Access 2002 that has related tables, a column with a plus sign (+) is added to access the related records, or subdatasheets, and is displayed as the first column. Subdatasheets are thoroughly explained in 6.

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Erdogan, L. Java Message Service (JMS) for J2EE New Riders Publishing, August 2002 Haefel, R.; Chappell, D. Java Message Service O Reilly & Associates, December 2000 Terry, S. Enterprise JMS Programming John Wiley & Sons, February 2002

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