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For weak scattering F 2 10 1 ; 1 the general expression for the spectrum of signal intensity uctuation (7.97) can be reduced to [41] I k 4h F iS k sin

Fig. 2-11 Interfacial polymerization; removal of polymer lm from the interface. From Morgan and Kwolek [1959 a,b] (by permission of Division of Chemical Education, American Chemical Society, Washington, DC and Wiley-Interscience, New York); an original photgraph, from which this gure was drawn, was kindly supplied by Dr. P. W. Morgan.

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organic and aqueous phases. Furthermore, high-molecular-weight polymer is formed at the interface regardless of the overall percent conversion based on the bulk amounts of the two reactants. The overall percent conversion can be increased by employing a stirred system as a means of increasing the total area of reacting interface. Several reaction parameters must be controlled in order for interfacial polymerization to proceed successfully. An inorganic base must be present in the aqueous phase to neutralize the by-product hydrogen chloride. If it were not neutralized the hydrogen chloride would tie up the diamine as its unreactive amine hydrochloride salt leading to greatly lowered reaction rates. The acid chloride may undergo hydrolysis to the unreactive acid at high concentrations of the inorganic base or at low polymerization rates. Hydrolysis not only decreases the polymerization rate but also greatly limits the polymer molecular weight, since it converts the diacid chloride into the diacid, which is unreactive at the temperatures employed in interfacial polymerization. The slower the polymerization rate, the greater the problem of hydrolysis as the acid chloride will have more time to diffuse through the interface and into the water layer. Thus acid hydrolysis prevents the use of the interfacial technique for the synthesis of polyesters from diols, since the reaction is relatively slow (k $ 10 3 L mol 1 s 1). The reaction of diacid chlorides and diamines is so fast (k $ 104 105 L mol 1 s 1) that hydrolysis is usually completely absent. The choice of the organic solvent is very important in controlling the polymer molecular weight, since it appears that the polymerization actually occurs on the organic solvent side of the interface in most systems. The reason for this is the greater tendency of the diamine to

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diffuse into the organic solvent compared to the diffusion of diacid chloride into the aqueous side of the interface (For some systems, eg, the reaction of the disodium salt of a dihydric phenol with a diacid chloride, the exact opposite is the case and polymerization occurs on the aqueous side of the interface) An organic solvent that precipitates the high-molecular-weight polymer but not the low-molecular-weight fractions is desirable Premature precipitation of the polymer will prevent the production of the desired high-molecular-weight product Thus, for example, xylene and carbon tetrachloride are precipitants for all molecular weights of poly (hexamethylene sebacate), while chloroform is a precipitant only for the high-molecularweight polymer Interfacial polymerization with the former organic solvents would yield only low-molecular-weight polymer The molecular weight distributions observed in interfacial polymerizations are usually quite different from the most probable distribution [Arai et al, 1985; Korshak, 1966; Morgan, 1965].

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